

For simplicity, this process is called clarification.
Unfortunately, coagulants are not effective at removing PFAS. The only effective methods for PFAS removal are adsorption (using granular activated carbon or ion exchange resins) or reverse osmosis filtration. These approaches are not used in traditional wastewater treatment because they are very expensive and are not required to meet registrations. However, potable reuse facilities will use these approaches to further treat wastewater effluent to drinking water standards. This is the future of water supply for arid areas like the southwest USA.
Also PS, the most commonly used coagulants are aluminum sulphate (alum) and ferric sulphate, which are not polymers. Polymers definitely are used (especially where I live) but they are more expensive and thus avoided when not needed.
Unfortunately, even if we stopped using PFAS entirely it will remain a legacy problem in wastewater and landfills because so many consumer products contain PFAS. That said, some places are working towards banning PFAS in new products and some of the really nasty ones are already banned in many countries. Here is Canada’s plan to phase PFAS out of industrial and consumer goods:
https://www.canada.ca/en/health-canada/services/chemicals-product-safety/per-polyfluoroalkyl-substances.html#a3